排序方式: 共有17条查询结果,搜索用时 15 毫秒
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用密度泛函理论(DFT)方法对一系列A3型咔咯锰(V)氧配合物进行了理论计算. 结果表明: 咔咯锰(V)-氧配合物中Mn―O键是由1 个σ键和2 个π键构成的叁键结构; 当咔咯中位取代基由推电子过渡到拉电子性质时, 咔咯骨架紧缩, Mn―O键缩短, 其拉曼光谱的伸缩振动峰往高波数移动; 取代基与氧原子的静电作用模式由正-负吸引转化为负-负排斥, 导致Mn―O键解离能ΔE减少, 即拉电子基团有利于增强咔咯锰(V)-氧配合物氧原子的活泼性. 相似文献
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王思广 周书华 叶云秀 叶震宇 冒亚军 M.Bouwhuis Y.Holler P.Lenisa D.Reggiani H.Marukyan P.Tait 《中国物理 C》2006,30(9):892-895
对于HERMES横向极化气体氢靶, 高能电子束流所激发的高频磁场会引发共振退极化. 本文就该极化度下降的产生机制进行研究, 并给出σ24共振点发生位置的测量结果, 并且将极化靶磁场的强度稳定在远离共振点处, 挽回了数据获取时极化度近3%的共振损失. 相似文献
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Yun-Xiu Zhao Jing-Hong Wen Ping Li Peng-Fang Zhang Prof. Su-Na Wang Prof. Da-Cheng Li Prof. Jian-Min Dou Prof. Yun-Wu Li Prof. Hui-Yan Ma Prof. Liqiang Xu 《Angewandte Chemie (International ed. in English)》2023,62(11):e202216950
To conquer the bottleneck of sluggish kinetics in cathodic oxygen reduction reaction (ORR) of metal-air batteries, catalysts with dual-active centers have stood out. Here, a “pre-division metal clusters” strategy is firstly conceived to fabricate a N,S-dual doped honeycomb-like carbon matrix inlaid with CoN4 sites and wrapped Co2P nanoclusters as dual-active centers (Co2P/CoN4@NSC-500). A crystalline {CoII 2 } coordination cluster divided by periphery second organic layers is well-designed to realize delocalized dispersion before calcination. The optimal Co2P/CoN4@NSC-500 executes excellent 4e− ORR activity surpassing the benchmark Pt/C. Theoretical calculation results reveal that the CoN4 sites and Co2P nanoclusters can synergistically quicken the formation of *OOH on Co sites. The rechargeable Zn-air battery (ZAB) assembled by Co2P/CoN4@NSC-500 delivers ultralong cycling stability over 1742 hours (3484 cycles) under 5 mA cm−2 and can light up a 2.4 V LED bulb for ≈264 hours, evidencing the promising practical application potentials in portable devices. 相似文献
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WANG Shao-Shun ZHANG Jie XIAO Chen-Guo YE Yun-Xiu CHENG Zheng-Dong ZHANG Xue-Qian LUO Qi XU Wan-Li XIONG Wei-Jun 《中国物理C(英文版)》1992,16(6):487-493
The pseudorapidity distributions of charged produced in pp collisions at 400GeV/c have been measured using LEBC films.Two-particle pseudorapidity correlations at fixed multiplicity have been studied.The experimental data was fitted by cluster model.It is found that the average cluster multiplicities as well as the cluster decay widths both vary slightly with charged multiplicity. 相似文献